Comparison of the Debye–Hückel and the Mean Spherical Approximation Theories for Electrolyte Solutions

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Comparison of the Debye–Huckel and the Mean Spherical Approximation Theories for Electrolyte Solutions

The thermodynamics of electrolyte solutions has been investigated by many scientists throughout the last century. While several theories have been presented, the most popular models for the electrostatic interactions are based on the Debye− Hückel and mean spherical approximation (MSA) theories. In this paper we investigate the differences between the Debye− Hückel and the MSA theories, and com...

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ژورنال

عنوان ژورنال: Industrial & Engineering Chemistry Research

سال: 2012

ISSN: 0888-5885,1520-5045

DOI: 10.1021/ie2029943